Shape and phase controlled synthesis of mesostructured carbon single crystals through mesoscale self-assembly of reactive monomicelles and their unprecedented exfoliation into single-layered carbon nanoribbons.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of colloid and interface science"
DOI: 10.1016/j.jcis.2019.09.098
Abstract: The formation of mesostructured polymer and carbon single-crystals is very difficult due to increased complexity of the energy hypersurface and the role of slowed-down kinetics. Here we reported the synthesis of ordered mesostructured phloroglucinol-formaldehyde single… read more here.
Keywords: layered carbon; carbon; single layered; carbon single ... See more keywords
Reduction of 2-H-substituted pyrrolinium cations: the carbon-carbon single bond in air stable 2,2'-bipyrrolidines as a two-electron-source.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc00891f
Abstract: Reduction of 2-H-substituted pyrrolinium cations via initially formed secondary radicals results in either dimerisation or H-abstracted products, while the outcome depends on the N-substituents. The resultant central carbon-carbon single bond in the dimerised 2,2'-bipyrrolidine derivatives… read more here.
Keywords: carbon; carbon carbon; substituted pyrrolinium; carbon single ... See more keywords