Direct Formation of Carbon(sp3)-Heteroatom Bonds from RhIII To Produce Methyl Iodide, Thioethers, and Alkylamines.
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DOI: 10.1021/jacs.7b04169
Abstract: Thermolysis of the RhIII-Me complex (DPEphos)RhMeI2 (1) results in reductive elimination of MeI. Mechanistic studies are consistent with SN2 attack by I- at the RhIII-Me group via two separate competing paths. Addition of sulfur and… read more here.
Keywords: sp3; direct formation; carbon sp3; formation carbon ... See more keywords