Pd-Catalyzed Umpolung of π–Allylpalladium Intermediates: Assembly of All-Carbon α-Vinyl Quaternary Aldehydes through C(sp3)–C(sp3) Coupling
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DOI: 10.1021/acscatal.8b03814
Abstract: Construction of sterically congested all-carbon quaternary centers represents a formidable challenge in synthetic chemistry. The method described herein provides direct and facile access to a series of structurally diverse and synthetically useful aliphatic aldehydes, bearing… read more here.
Keywords: vinyl quaternary; catalyzed umpolung; carbon; vinyl ... See more keywords