Towards clustered carbonyl cations [M3(CO)14]2+ (M = Ru, Os): the need for innocent deelectronation
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DOI: 10.1039/d2sc02358j
Abstract: To access the hitherto almost unknown class of clustered transition metal carbonyl cations, the trimetal dodecacarbonyls M3(CO)12 (M = Ru, Os) were reacted with the oxidant Ag+[WCA]−, but yielded the silver complexes [Ag{M3(CO)12}2]+[WCA]− (WCA =… read more here.
Keywords: cations need; carbonyl cations; need innocent; innocent deelectronation ... See more keywords
Generation and Reactions of ε-Carbonyl Cations via Group 13 Catalysis
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DOI: 10.3390/molecules27103078
Abstract: The generation of ε-carbonyl cations and their reactions with nucleophiles is accomplished readily without transition metal cation stabilization, using the ε-bromide dienoate or dienone starting materials and GaCl3 or InCl3 catalysis. Arene nucleophiles are somewhat… read more here.
Keywords: carbonyl cations; catalysis; reactions carbonyl; cations via ... See more keywords