Isomerism in Molecular Metal Carbonyl Clusters
Sign Up to like & getrecommendations! Published in 2024 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.202400220
Abstract: The present microreview focuses on different typologies of isomerism documented along the years for metal carbonyl clusters (MCCs), and outlines their analogies to other classes of ligand‐protected molecular clusters and nanoclusters. Isomerism in molecular MCCs… read more here.
Keywords: isomerism; metal; isomerism molecular; metal carbonyl ... See more keywords
Bimetallic Fe–Ir and Trimetallic Fe–Ir–Au Carbonyl Clusters Containing Hydride and/or Phosphine Ligands: Syntheses, Structures and DFT Studies
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Cluster Science"
DOI: 10.1007/s10876-020-01839-y
Abstract: The reaction of [HFe 4 (CO) 12 (IrCOD)] 2− ( 1 ) with CO at ambient conditions afforded [HFe 4 Ir(CO) 14 ] 2− ( 2 ), that, in turn, reacted with HBF 4 ·Et… read more here.
Keywords: pph; carbonyl clusters; trimetallic carbonyl; hfe ... See more keywords
Pt and Pt/Sn carbonyl clusters as precursors for the synthesis of supported metal catalysts for the base-free oxidation of HMF
Sign Up to like & getrecommendations! Published in 2019 at "Applied Catalysis A: General"
DOI: 10.1016/j.apcata.2019.117279
Abstract: Abstract In the present work, Pt and Pt/Sn nanoparticles (NPs), synthesized from carbonyl cluster precursors were deposited on TiO2 and the resulting materials were tested as catalysts in selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic… read more here.
Keywords: carbonyl clusters; clusters precursors; oxidation; base free ... See more keywords
Iron carbonyl clusters with ECl2 units (E = P, As)
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2017.03.008
Abstract: Abstract Reaction of [PPN][HFe(CO) 4 ] (PPN = bis(triphenylphosphine)iminium) with PCl 3 in a 1:1 ratio produced small amounts of [PPN][P{Fe(CO) 4 } 2 Cl 2 ] ([PPN][ Ia ]). Reaction of [Et 4 N][HFe(CO) 4 ]… read more here.
Keywords: ppn; carbonyl clusters; clusters ecl2; iron carbonyl ... See more keywords