Bimetallic Fe–Ir and Trimetallic Fe–Ir–Au Carbonyl Clusters Containing Hydride and/or Phosphine Ligands: Syntheses, Structures and DFT Studies
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Cluster Science"
DOI: 10.1007/s10876-020-01839-y
Abstract: The reaction of [HFe 4 (CO) 12 (IrCOD)] 2− ( 1 ) with CO at ambient conditions afforded [HFe 4 Ir(CO) 14 ] 2− ( 2 ), that, in turn, reacted with HBF 4 ·Et… read more here.
Keywords: pph; carbonyl clusters; trimetallic carbonyl; hfe ... See more keywords
Pt and Pt/Sn carbonyl clusters as precursors for the synthesis of supported metal catalysts for the base-free oxidation of HMF
Sign Up to like & getrecommendations! Published in 2019 at "Applied Catalysis A: General"
DOI: 10.1016/j.apcata.2019.117279
Abstract: Abstract In the present work, Pt and Pt/Sn nanoparticles (NPs), synthesized from carbonyl cluster precursors were deposited on TiO2 and the resulting materials were tested as catalysts in selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic… read more here.
Keywords: carbonyl clusters; clusters precursors; oxidation; base free ... See more keywords
Iron carbonyl clusters with ECl2 units (E = P, As)
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2017.03.008
Abstract: Abstract Reaction of [PPN][HFe(CO) 4 ] (PPN = bis(triphenylphosphine)iminium) with PCl 3 in a 1:1 ratio produced small amounts of [PPN][P{Fe(CO) 4 } 2 Cl 2 ] ([PPN][ Ia ]). Reaction of [Et 4 N][HFe(CO) 4 ]… read more here.
Keywords: ppn; carbonyl clusters; clusters ecl2; iron carbonyl ... See more keywords