Electrochemical CO2 Reduction Using a New Ru‐NAD Type Bis Carbonyl Complex
Sign Up to like & getrecommendations! Published in 2024 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.202400657
Abstract: A new ruthenium(II) NAD (NAD = Nicotinamide Adenine Dinucleotide) type bis‐carbonyl complex, [Ru(bpy)(pbn)(CO)2]2+ [pbn = 2‐(pyridin‐2‐yl)benzo[b]‐1,5‐naphthyridine; bpy = 2,2'‐bipyridine] [1]2+, was successfully synthesized and fully characterized by single‐crystal X‐ray structural analysis, ESI‐MS, IR and NMR… read more here.
Keywords: type bis; type; bpy; carbonyl complex ... See more keywords
Luminescent rhenium(I) carbonyl complex with redox noninnocent ONS donor azo-phenol ligand: Synthesis, X-ray structure, photophysical properties and live cell imaging
Sign Up to like & getrecommendations! Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2019.01.004
Abstract: Abstract Herein, we have synthesized a new fluorescent rhenium(I) carbonyl complex 1, bearing {Re(CO)3}+ core with ONS donor thioether containing azo-phenol redox noninnocent ligand. The distorted octahedral geometry of the complex is confirmed by single… read more here.
Keywords: redox noninnocent; rhenium carbonyl; carbonyl complex; azo phenol ... See more keywords
A Diiron(I/II) μ-1,2-Carbonyl Complex Relevant to CO Binding on Fe(111).
Sign Up to like & getrecommendations! Published in 2025 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.5c00759
Abstract: Fischer-Tropsch conversion of syngas to hydrocarbons is proposed to begin with CO binding to the iron surface of the catalyst. CO adsorption on various iron facets of relevance to the Fischer-Tropsch process suggest that the… read more here.
Keywords: iron; complex relevant; diiron carbonyl; carbonyl complex ... See more keywords
A ligand-modulated photostable Mn(I)-carbonyl complex for preferential conversion of CO2 to CO in water.
Sign Up to like & getrecommendations! Published in 2024 at "Chemical communications"
DOI: 10.1039/d4cc03202k
Abstract: A strategically designed redox-active ligand ensures proper electronic balance in an Mn(I)-carbonyl template to induce photostability and water solubility. This newly designed Mn-carbonyl complex showcased rapid CO2 reduction with preferential production of CO (faradaic efficiency… read more here.
Keywords: ligand modulated; carbonyl; modulated photostable; water ... See more keywords
A main-group metal carbonyl complex: Structure and isomerization to a carbene-stabilized tin atom.
Sign Up to like & getrecommendations! Published in 2025 at "Science"
DOI: 10.1126/science.ady0247
Abstract: In contrast to transition elements, s- and p-block metal compounds that coordinate carbon monoxide (CO) under near-ambient conditions are elusive. Here, we report an isolable, crystalline main-group metal carbonyl complex and its isomerization to a… read more here.
Keywords: metal; metal carbonyl; carbene; main group ... See more keywords