Theoretical analysis of frontier orbitals, electronic transitions, and global reactivity descriptors of M(CO)4L2 type metal carbonyl complexes: a DFT/TDDFT study
Sign Up to like & getrecommendations! Published in 2018 at "Structural Chemistry"
DOI: 10.1007/s11224-018-1231-0
Abstract: Metal carbonyl complexes, which have been known as effective catalysts since early days, find use in many fields both directly and indirectly. Although the use of metal carbonyl complexes as bio-probe and protein labeling agent… read more here.
Keywords: metal carbonyl; carbonyl complexes; reactivity; theoretical analysis ... See more keywords
Re(I) carbonyl complexes: Multimodal platforms for inorganic chemical biology
Sign Up to like & getrecommendations! Published in 2017 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2017.05.004
Abstract: Bio-imaging, by enabling the visualization of biomolecules of interest, has proved to be highly informative in the study of biological processes. Although fluorescence microscopy is probably one of the most used techniques, alternative methods of… read more here.
Keywords: complexes multimodal; platforms inorganic; carbonyl complexes; biology ... See more keywords
Chromium carbonyl complexes with aryl mono- and oligogermanes: Ability for haptotropic rearrangement
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2019.07.012
Abstract: Abstract The intra- and inter molecular inter-ring η 6 ⇌ η 6 -haptotropic rearrangements (IRHR), occurring by involving interactions to Ge atoms in arylgermanes, were investigated theoretically and experimentally. The new methods for the synthesis… read more here.
Keywords: carbonyl complexes; oligogermanes ability; aryl mono; chromium carbonyl ... See more keywords
Synthesis and catalytic reactivity in Friedel–Crafts acylations of monobridged bis(cyclopentadienyl)molybdenum(I) carbonyl complexes
Sign Up to like & getrecommendations! Published in 2018 at "Polyhedron"
DOI: 10.1016/j.poly.2018.03.021
Abstract: Abstract When the monobridged biscyclopentadienes (C5H5)R(C5H5) [R = C(CH3)2 (1), Si(CH3)2 (2), C(CH2)5 (3)] reacted with Mo(CO)6 in refluxing xylene, the corresponding complexes [(η5-C5H4)2R][Mo(CO)3]2 [R = C(CH3)2 (4), Si(CH3)2 (5), C(CH2)5 (6)] were obtained. These complexes were separated by… read more here.
Keywords: molybdenum carbonyl; cyclopentadienyl molybdenum; bis cyclopentadienyl; carbonyl complexes ... See more keywords
Computational Design of Rhenium(I) Carbonyl Complexes for Anticancer Photodynamic Therapy
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.1c03130
Abstract: New Re(I) carbonyl complexes are proposed as candidates for photodynamic therapy after investigating the effects of the pyridocarbazole-type ligand conjugation, addition of substituents to this ligand, and replacement of one CO by phosphines in [Re(pyridocarbazole)(CO)3(pyridine)]… read more here.
Keywords: energy; carbonyl complexes; ligand; photodynamic therapy ... See more keywords
Synthesis and Chemistry of Ammonioethenyl and Phosphonioethenyl Ligands in Zwitterionic Dirhenium Carbonyl Complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01471
Abstract: New zwitterionic dirhenium carbonyl complexes containing ammonioethenyl and phosphonioethenyl ligands have been synthesized and studied. The reaction of Re2(CO)10 with C2H2 and Me3NO yielded the dirhenium complex Re2(CO)9(NMe3) (6) and the new zwitterionic complex Re2(CO)9[η1-E-2-CH═CH(NMe3)]… read more here.
Keywords: dirhenium carbonyl; re2; carbonyl complexes; chemistry ... See more keywords
CO Release from N,C,S-Pincer Iron(III) Carbonyl Complexes Induced by Visible-to-NIR Light Irradiation: Mechanistic Insight into Effects of Axial Phosphorus Ligands.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b01407
Abstract: Light-induced CO release from newly synthesized N,C,S-pincer iron(III) carbonyl complexes with two phosphorus ligands- trans-[Fe(L-κ3 N,C,S)(CO)(PR2R')2]PF6 ([1]PF6, R = Me, R' = Ph; [2]PF6, R = R' = Me; [3]PF6, R = R' = OEt)-were… read more here.
Keywords: pf6; pf6 pf6; carbonyl complexes; iii carbonyl ... See more keywords
Comment on “Topological Analysis of the Electron Density in the Carbonyl Complexes M(CO)8 (M = Ca, Sr, Ba)”
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DOI: 10.1021/acs.organomet.0c00419
Abstract: We question the statement of a recent publication ( Organometallics 2020, 39, 132, DOI: 10.1021/acs.organomet.9b00699) that the M → CO π backdonation in the alkaline earth carbonyl complexes M(CO)8... read more here.
Keywords: electron density; carbonyl complexes; comment topological; topological analysis ... See more keywords
Molecular engineered rhenium(i) carbonyl complexes to promote photoisomerization of coordinated stilbene-like ligands in the visible region.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt02721h
Abstract: Novel fac-[Re(CO)3(dmcb)(trans-stpyR)]+ complexes, dmcb = 4,4'-dimethoxycarbonyl-2,2'-bipyridine, have been judiciously engineered to absorb at lower energies and sensitize trans-4-styrylpyridine (trans-stpy) or trans-4-(4-cyano)styrylpyridine (trans-stpyCN) photoisomerizable ligands up to 436 nm of irradiation. Moreover, these complexes exhibit remarkable… read more here.
Keywords: stilbene like; molecular engineered; rhenium carbonyl; engineered rhenium ... See more keywords
Ruthenium carbonyl complexes with pyridine-alkoxide ligands: synthesis, characterization and catalytic application in dehydrogenative oxidation of alcohols
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DOI: 10.1039/c8nj03706j
Abstract: Several new trinuclear ruthenium carbonyl complexes chelated with 6-bromopyridine alcohol ligands, [6-bromopyC(CH2)4O]Ru3(CO)9 (1a), [6-bromopyC(CH2)5O]Ru3(CO)9 (1b), [6-bromopyC(Me)2O]Ru3(CO)9 (1c) and [6-bromopyCMeC6H5O]Ru3(CO)9 (1d), were synthesized by the reaction of Ru3(CO)12 with 6-bromopyC(CH2)4OH (L1H), 6-bromopyC(CH2)5OH (L2H), 6-bromopyC(Me)2OH (L3H) and… read more here.
Keywords: carbonyl complexes; ruthenium carbonyl; ru3; bromopyc ch2 ... See more keywords
Dissecting conjugation and electronic effects on the linear and non-linear optical properties of rhenium(i) carbonyl complexes
Sign Up to like & getrecommendations! Published in 2022 at "Physical Chemistry Chemical Physics"
DOI: 10.1039/d2cp03844g
Abstract: Herein, we report a theoretical and experimental analysis of the conjugation and electronic effects on the one-photon (1PA) and two-photon absorption (2PA) properties of a series of Re(i) carbonyl complexes with terpyridine-based ligands. An excellent… read more here.
Keywords: electronic effects; non linear; conjugation electronic; photon ... See more keywords