Non-innocent cyanido ligands: tetracyanidoferrate(-II) as carbonyl copycat.
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DOI: 10.1039/d2dt00833e
Abstract: While a negative oxidation state occurs rarely for metals in general, this is commonly known for metal carbonyl anions, i.e. carbonyl metalates. Although CO and CN- are isoelectronic, cyanidometalates usually do not exhibit metal centers… read more here.
Keywords: cyanido ligands; ligands tetracyanidoferrate; carbonyl copycat; tetracyanidoferrate carbonyl ... See more keywords