Catalytic regeneration of a Th-H bond from a Th-O bond through a mild and chemoselective carbonyl hydroboration.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc05030a
Abstract: Here we present an unprecedented chemoselective hydroboration for aldehydes and ketones catalysed by actinides. The reaction features a very low catalyst loading (0.1-0.004 mol%) and quantitative product formation in less than 15 minutes, at room… read more here.
Keywords: bond; catalytic regeneration; regeneration bond; hydroboration ... See more keywords
Coinage metal amido and thiolate SNS complexes: consequences of catalyst speciation in Cu(I)-catalysed carbonyl hydroboration.
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DOI: 10.1039/d2cc06077a
Abstract: Three new IPr-Ag- and -Au-SNS amido and thiolate complexes were synthesized and compared to their previously reported Cu analogues as carbonyl hydroboration catalysts (IPr = bis(2,6-diisopropylphenyl)imidazol-2-ylidene). Although these complexes showed no catalytic activity, treatment of… read more here.
Keywords: carbonyl hydroboration; amido thiolate; amido; sns ... See more keywords