Enantioselective Metal-Catalyzed Reductive Coupling of Alkynes with Carbonyl Compounds and Imines: Convergent Construction of Allylic Alcohols and Amines.
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DOI: 10.1021/acscatal.2c02444
Abstract: The use of alkynes as vinylmetal pronucleophiles in intermolecular enantioselective metal-catalyzed carbonyl and imine reductive couplings to form allylic alcohols and amines is surveyed. Related hydrogen auto-transfer processes, wherein alcohols or amines serve dually as… read more here.
Keywords: carbonyl imine; enantioselective metal; alcohols amines; allylic alcohols ... See more keywords