Catalytic C-C Cleavage/Alkyne-Carbonyl Metathesis Sequence of Cyclobutanones.
Sign Up to like & getrecommendations! Published in 2020 at "Organic letters"
DOI: 10.1021/acs.orglett.0c01317
Abstract: A ring-opening/alkyne-carbonyl metathesis sequence of alkyne-tethered cyclobutanones catalyzed by AgSbF6 is realized for the first time to furnish multisubstituted naphthyl ketones under mild conditions. A range of substrates decorated with various substituents at different positions… read more here.
Keywords: alkyne carbonyl; carbonyl metathesis; metathesis; metathesis sequence ... See more keywords
Photoinitiated carbonyl-metathesis: deoxygenative reductive olefination of aromatic aldehydes via photoredox catalysis† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c9sc00711c
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Science"
DOI: 10.1039/c9sc00711c
Abstract: Carbonyl–carbonyl olefination, known as McMurry reaction, represents a powerful strategy for the construction of olefins. read more here.
Keywords: deoxygenative reductive; metathesis deoxygenative; carbonyl metathesis; olefination ... See more keywords