Articles with "carbonylation" as a keyword



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Cerebrospinal fluid protein carbonylation identifies oxidative damage in autoimmune demyelination

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Published in 2017 at "Annals of Clinical and Translational Neurology"

DOI: 10.1002/acn3.379

Abstract: Oxidative damage occurs in multiple sclerosis, but is difficult to identify antemortem and remains an unknown contributor to disease progression. Carbonylation is a quantitative measure of protein oxidation. Cerebrospinal fluid samples from multiple sclerosis patients… read more here.

Keywords: protein; oxidative damage; carbonylation; cerebrospinal fluid ... See more keywords
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Carbonylation of Aziridines as a Powerful Tool for the Synthesis of Functionalized β‐Lactams

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Published in 2017 at "European Journal of Organic Chemistry"

DOI: 10.1002/ejoc.201700698

Abstract: Within heterocyclic chemistry, β-lactams comprise an extraordinary class of strained compounds, recognized for their biological importance as potent antibiotics and their chemical value as flexible building blocks for the construction of diverse nitrogen-containing structures. Among… read more here.

Keywords: tool synthesis; powerful tool; carbonylation aziridines; chemistry ... See more keywords

Carbonylation of Methanol Over Nickel-Copper Based Supported Catalysts

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Published in 2020 at "Catalysis Letters"

DOI: 10.1007/s10562-020-03368-9

Abstract: The results are reported concerning the production of methyl acetate in the halide-free vapor-phase methanol carbonylation (MC) over NiCl2–CuCl2 based catalysts on activated carbons and honeycomb cordierite supports. The formation of the MeOAc with the… read more here.

Keywords: carbonylation; methanol; nicl2 cucl2; nickel copper ... See more keywords
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Complex Nature of Protein Carbonylation Specificity After Metal-Catalyzed Oxidation

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Published in 2017 at "Pharmaceutical Research"

DOI: 10.1007/s11095-017-2103-9

Abstract: ABSTRACTPurposeProtein carbonylation is an irreversible modification of Lys, Arg, Thr and Pro amino acids under conditions of oxidative stress. Previous studies have reported specific carbonylated residues in purified recombinant albumins, albeit with a lack of… read more here.

Keywords: carbonylation; site; protein carbonylation; metal catalyzed ... See more keywords
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Role of Glutathione-S-Transferase Polymorphism on Arsenic-Induced Protein Carbonylation and Urinary Deoxy Guanosine Status

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Published in 2019 at "Exposure and Health"

DOI: 10.1007/s12403-019-00319-7

Abstract: Oxidative stress is significantly associated with chronic arsenic exposure in persons exposed to moderate-to-high level of environmental arsenic. However, the response varies widely among persons within similar exposure level. To study whether Glutathione-S-Transferase (GST) gene… read more here.

Keywords: status; arsenic; protein carbonylation; exposure ... See more keywords
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Novel heterogeneous Rh-incorporated graphitic-carbon nitride for liquid-phase carbonylation of methanol to acetic acid

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Published in 2017 at "Catalysis Communications"

DOI: 10.1016/j.catcom.2017.06.007

Abstract: Abstract A novel heterogeneous rhodium-incorporated graphitic carbon nitride (Rh-g-C3N4) was investigated for a liquid-phase carbonylation of methanol to acetic acid (AA) to overcome disadvantages of the commercialized Rh-based homogeneous catalysts. The heterogeneous Rh-g-C3N4 catalyst showed… read more here.

Keywords: novel heterogeneous; liquid phase; phase carbonylation; carbonylation ... See more keywords
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Effect of mass-transfer control on HY zeolites for dimethoxymethane carbonylation to methyl methoxyacetate

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Published in 2018 at "Catalysis Today"

DOI: 10.1016/j.cattod.2018.02.004

Abstract: Abstract A series of hierarchical HY zeolites were prepared by using sequential acid (H4EDTA) and alkaline (NaOH and NH4OH) solution treatments. The nitrogen adsorption-desorption analysis proved that the mesoporous structure was definitely formed with the… read more here.

Keywords: carbonylation; methoxyacetate; mass transfer; dmm conversion ... See more keywords
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Mechanistic understanding of methanol carbonylation: Interfacing homogeneous and heterogeneous catalysis via carbon supported IrLa

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Published in 2018 at "Journal of Catalysis"

DOI: 10.1016/j.jcat.2018.02.022

Abstract: Abstract The creation of heterogeneous analogs to homogeneous catalysts is of great importance to many industrial processes. Acetic acid synthesis via the carbonylation of methanol is one such process and it relies on a difficult-to-separate… read more here.

Keywords: methanol carbonylation; single site; catalysis; carbonylation ... See more keywords
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Direct conversion of dimethyl ether and CO to acetone via coupling carbonylation and ketonization

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Published in 2021 at "Journal of Catalysis"

DOI: 10.1016/j.jcat.2021.03.006

Abstract: Abstract Acetone is currently produced by large amount of propylene and benzene, and its synthesis from a cheap and non-petroleum material has not yet been reported. Here, we present a new method for acetone production,… read more here.

Keywords: dimethyl ether; conversion; acetone; carbonylation ... See more keywords
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Synthesis of 2,5-furandicarboxylic acid by catalytic carbonylation of renewable furfural derived 5-bromofuroic acid

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Published in 2018 at "Molecular Catalysis"

DOI: 10.1016/j.mcat.2018.06.015

Abstract: Abstract 2,5-Furandicarboxylic acid (FDCA) is regarded as a biomass based alternative to p-phthalic acid in polymer industry. Although it can be produced through catalytic oxidation of hydroxylmethyl furfural (HMF), HMF itself is currently produced in… read more here.

Keywords: renewable furfural; furandicarboxylic acid; carbonylation; bromofuroic acid ... See more keywords
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Seed-assisted synthesis of FER/MOR composite zeolite and its specific catalytic application in carbonylation reaction

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Published in 2018 at "Microporous and Mesoporous Materials"

DOI: 10.1016/j.micromeso.2017.07.058

Abstract: Abstract A series of FER/MOR composite zeolites were synthesized through seed-assisted organic template free route. And the FER/MOR composite zeolites exhibited specific catalytic performance in the dimethyl ether carbonylation to methyl acetate reaction. SEM images… read more here.

Keywords: carbonylation; fer mor; seed; mor composite ... See more keywords