Nickel-Catalyzed Carbonylation of Cyclopropanol with Benzyl Bromide for Multisubstituted Cyclopentenone Synthesis.
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DOI: 10.1021/acs.orglett.2c00798
Abstract: Herein, we reported a Ni-catalyzed carbonylation of cyclopropanol with benzyl bromide to afford multisubstituted cyclopentenone under 1 atm of CO. The reaction proceeds through cascade carbonylation of benzyl bromides, followed by generation of nickel homoenolate… read more here.
Keywords: carbonylation; cyclopropanol benzyl; carbonylation cyclopropanol; benzyl ... See more keywords