Dinickel catalyzed carbonylation reactions using metal carbonyl reagents as CO sources
Sign Up to like & getrecommendations! Published in 2019 at "Tetrahedron"
DOI: 10.1016/j.tet.2019.04.064
Abstract: Abstract Dinickel complexes promote stoichiometric Pauson–Khand reactions of enynes and CO (g). However, catalytic turnover is precluded by the strong binding of CO to the Ni2 active site. This article describes the use of M(CO)x… read more here.
Keywords: carbonylation reactions; reactions using; dinickel catalyzed; catalyzed carbonylation ... See more keywords
Realizing Metal-Free Carbene-Catalyzed Carbonylation Reactions with CO.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c09938
Abstract: Many organic and main-group compounds, usually acids or bases, can accelerate chemical reactions when used in substoichiometric quantities, a process known as organocatalysis. In marked contrast, very few of these compounds are able to activate… read more here.
Keywords: carbonylation reactions; carbonylation; carbene; realizing metal ... See more keywords
5-Bromo-norborn-2-en-7-one derivatives as a carbon monoxide source for palladium catalyzed carbonylation reactions
Sign Up to like & getrecommendations! Published in 2019 at "RSC Advances"
DOI: 10.1039/c9ra06594f
Abstract: Norbornenone (5b), obtained from the reaction of 2,5-dimethyl-3,4-diphenylcyclopentadienone dimer (3) with bromomaleic anhydride (4b), provides an excellent base-triggered source of carbon monoxide for palladium-catalysed carbonylation reactions. read more here.
Keywords: palladium; source; carbon monoxide; carbonylation reactions ... See more keywords
Synergism between iron porphyrin and dicationic ionic liquids: tandem CO2 electroreduction-carbonylation reactions.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc03641j
Abstract: Here, we report a simple procedure that drastically reduces the electrochemical E(FeI/Fe0) and E0cat of the commercially available iron(III) tetraphenylporphyrin chloride (FeIIITPP·Cl) catalyst via a synergetic effect with the imidazolium dications of the ionic liquid… read more here.
Keywords: carbonylation reactions; iron porphyrin; synergism iron; tandem co2 ... See more keywords
PdI2-Based Catalysis for Carbonylation Reactions: A Personal Account
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DOI: 10.3390/catal9070610
Abstract: In this account, we review our efforts in the field of carbonylation reactions promoted by palladium iodide-based catalysts, which have proven to be particularly efficient in diverse kinds of carbonylation processes (oxidative carbonylations as well… read more here.
Keywords: based catalysis; account; carbonylation reactions; carbonylation ... See more keywords