Palladium Catalyzed Carbonylative Coupling of Alkyl Boron Reagents with Bromodifluoroacetamides
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DOI: 10.1021/acscatal.8b00420
Abstract: A catalytic protocol for the preparation of α,α-difluoro-β-alkyl-β-ketoamides is developed employing a Pd-mediated carbonylative Suzuki coupling between alkylboron reagents and bromodifluoroacetamides with COgen as the CO source. The reaction reveals good functional group tolerance providing… read more here.
Keywords: alkyl; carbonylative coupling; coupling alkyl; palladium catalyzed ... See more keywords
Palladium-Catalyzed Regioselective Carbonylative Coupling/Amination of Aryl Iodides with Unactivated Alkenes: Efficient Synthesis of β-Aminoketones
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DOI: 10.1021/acscatal.9b00774
Abstract: The carbonylative coupling of aryl halides with unactivated alkenes remains a challenge, because of the low reactivity of acyl-palladium intermediate to the olefins. In this paper, a palladium-cata... read more here.
Keywords: catalyzed regioselective; carbonylative coupling; palladium catalyzed; regioselective carbonylative ... See more keywords
27 Years of Catalytic Carbonylative Coupling Reactions in Hungary (1994–2021)
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DOI: 10.3390/molecules27020460
Abstract: Palladium-catalyzed carbonylation reactions, in the presence of nucleophiles, serve as very potent tools for the conversion of aryl and alkenyl halides or halide equivalents to carboxylic acid derivatives or to other carbonyl compounds. There are… read more here.
Keywords: reactions hungary; years catalytic; carbonylative coupling; coupling reactions ... See more keywords