Photoelectron Velocity Map Imaging Spectroscopy of Heteronuclear Metal–Nickel Carbonyls MNi(CO)n− (M = Sc, Y; n = 2–6)
Sign Up to like & getrecommendations! Published in 2017 at "Topics in Catalysis"
DOI: 10.1007/s11244-017-0875-0
Abstract: The chemical bonding and electronic structure of heteronuclear metal–nickel carbonyls MNi(CO)n− (M = Sc, Y; n = 2–6) have been investigated by mass-selected photoelectron velocity map imaging spectroscopy and quantum chemical calculations. Two CO bonding modes (side-on-bonded and terminal… read more here.
Keywords: metal nickel; carbonyls; spectroscopy; heteronuclear metal ... See more keywords
Spatial distributions of airborne di-carbonyls in urban and rural areas in China
Sign Up to like & getrecommendations! Published in 2017 at "Atmospheric Research"
DOI: 10.1016/j.atmosres.2016.11.008
Abstract: Abstract Gaseous glyoxal and methylglyoxal concentrations were characterized in nine cities of China during 2010–2011. The average summer (winter) glyoxal and methylglyoxal concentrations were 36.4–178.4 (12.3–241.4) and 67.8–359.4 (28.4–530.0) ng/m 3 , respectively. In summer,… read more here.
Keywords: glyoxal; winter; glyoxal methylglyoxal; carbonyls ... See more keywords
Formaldehyde, acrolein and other carbonyls in dwellings of university students. Levels and source characterization.
Sign Up to like & getrecommendations! Published in 2021 at "Chemosphere"
DOI: 10.1016/j.chemosphere.2021.132429
Abstract: Fifteen carbonyl compounds were investigated in the living rooms and bedrooms of 25 university student flats in the urban area of Ciudad Real (Central Southern Spain) in wintertime. Carbonyls were sampled using Radiello ® passive… read more here.
Keywords: living rooms; acetone; carbonyls; formaldehyde ... See more keywords
Malondialdehyde interferes with the formation and detection of primary carbonyls in oxidized proteins
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DOI: 10.1016/j.redox.2019.101277
Abstract: Carbonylation is one of the most remarkable expressions of the oxidative damage to proteins and the DNPH method the most common procedure to assess protein oxidation in biological samples. The present study was elicited by… read more here.
Keywords: interferes formation; malondialdehyde interferes; carbonyls; formation detection ... See more keywords
Triflic acid catalysed regioselective synthesis of substituted naphthalenes by benzannulation of carbonyls with alkynes
Sign Up to like & getrecommendations! Published in 2021 at "Tetrahedron"
DOI: 10.1016/j.tet.2021.132214
Abstract: Abstract An interesting and facile triflic acid catalysed annulation of α-aryl carbonyls with arylalkynes is presented for the regioselective synthesis of substituted naphthalenes. The annulation reaction involves a sequence of electrophilic attack of carbonyl on… read more here.
Keywords: triflic acid; synthesis substituted; carbonyls; acid catalysed ... See more keywords
Deoxygenative Haloboration and Enantioselective Chloroboration of Carbonyls.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c11024
Abstract: Deoxygenative difunctionalization of carbonyls affords a straightforward and effective route to construct geminal dual functionalized motifs. However, the research in this field is very challenging due to the strong bond dissociation energies of the C-O… read more here.
Keywords: enantioselective chloroboration; deoxygenative haloboration; carbonyls; chloroboration carbonyls ... See more keywords
Photochemistry of transition metal carbonyls.
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DOI: 10.1039/d1cs00826a
Abstract: The purpose of this Tutorial Review is to outline the fundamental photochemistry of metal carbonyls, and to show how the advances in technology have increased our understanding of the detailed mechanisms, particularly how relatively simple… read more here.
Keywords: photochemistry transition; transition metal; metal carbonyls; carbonyls ... See more keywords
Influence of battery power setting on carbonyl emissions from electronic cigarettes
Sign Up to like & getrecommendations! Published in 2020 at "Tobacco Induced Diseases"
DOI: 10.18332/tid/126406
Abstract: INTRODUCTION Although e-cigarettes share common features such as power units, heating elements and e-liquids, the variability in design and possibility for customization represent potential risks for consumers. A main health concern is the exposure to… read more here.
Keywords: battery power; power; carbonyls; power setting ... See more keywords