Palladium-Catalyzed Domino Heck/Aryne Carbopalladation/C-H Functionalization: Synthesis of Heterocycle-Fused 9,10-Dihydrophenanthrenes.
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DOI: 10.1021/acs.orglett.6b03833
Abstract: A novel palladium-catalyzed domino Heck/aryne carbopalladation/C-H functionalization reaction using in situ generated arynes has been developed in which three new C-C bonds and a carbon quaternary center are formed. This methodology affords moderate to excellent… read more here.
Keywords: carbopalladation functionalization; domino heck; palladium catalyzed; heck aryne ... See more keywords