Stereoselective Carboperfluoroalkylation of Internal Alkynes: Mechanistic Insights
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DOI: 10.1007/s11244-017-0743-y
Abstract: A Pd-catalyzed difunctionalization of internal alkynes combining boronic acids and perfluoroalkyl iodides under mild conditions is described here. Tetrasubstituted olefins containing perfluoroalkyl groups are synthesized in high yields in a regio- and stereoselective manner. Mechanistic… read more here.
Keywords: alkynes mechanistic; internal alkynes; carboperfluoroalkylation internal; stereoselective carboperfluoroalkylation ... See more keywords