Below the 12-vertex: 10-vertex carborane anions as non-corrosive, halide free, electrolytes for rechargeable Mg batteries.
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DOI: 10.1039/c7cc01570d
Abstract: The development of practical Mg based batteries is limited by the lack of a library of suitable electrolytes. Recently a 12-vertex closo-carborane anion based electrolyte has been shown to be the first electrolyte for Mg… read more here.
Keywords: carborane anions; closo carborane; vertex closo; halide free ... See more keywords
Cesium carbonate mediated C-H functionalization of perhalogenated 12-vertex carborane anions.
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DOI: 10.1039/d2cc00173j
Abstract: C-H functionalization of undecahalogenated carborane anions, [HCB11X11-] (X = Cl, Br, I), is performed with Cs2CO3 in acetonitrile. We show that the requisite Cl, Br and I carborane dianions can all be efficiently accessed with… read more here.
Keywords: mediated functionalization; carbonate mediated; functionalization; carborane anions ... See more keywords