Synthesis of new nido-carborane based carboxylic acids and amines
Sign Up to like & getrecommendations! Published in 2018 at "Polyhedron"
DOI: 10.1016/j.poly.2018.07.009
Abstract: Abstract A series of new nido-carborane based carboxylic acids 10-HOOC(CH2)n(Me)S-7,8-C2B9H11 (n = 1–4) was prepared by alkylation of tetrabutylammonium salt of 10-methylthio-7,8-dicarba-nido-caborane with ω-halogenoalkyl esters or nitriles followed by acid hydrolysis. Likewise nido-carborane based amines 10-H2N(CH2)n(Me)S-7,8-C2B9H11 (n = 2,… read more here.
Keywords: carborane based; new nido; carboxylic acids; based carboxylic ... See more keywords
o-Carborane based and atomically-precise metal clusters as hypergolic materials.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c04638
Abstract: Atomically-precise o-carboranealkynyl-protected clusters [Ag14(C4B10H11)12(CH3CN)2]•2NO3- (CBA-Ag) and [Cu6Ag8(C4B10H11)12Cl]NO3- (CBA-CuAg) have been found to exhibit hypergolic activity, such that they are capable of spontaneous ignition and combustion upon contact with the white fuming nitric acid oxidizer. In… read more here.
Keywords: atomically precise; carborane based; based atomically; precise metal ... See more keywords
Carborane based mesoporous nanoparticles as a potential agent for BNCT
Sign Up to like & getrecommendations! Published in 2021 at "Materials Chemistry Frontiers"
DOI: 10.1039/d0qm00867b
Abstract: In view of the unique physical and chemical properties, boron rich carboranes have been preliminarily considered as candidates for boron neutron capture therapy (BNCT) in treatment of malignancies. However, before effectively implementing BNCT without damaging… read more here.
Keywords: based mesoporous; boron; agent; carborane based ... See more keywords
o-Carborane-based fluorophores as efficient luminescent systems both as solids and as water-dispersible nanoparticles.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc07211k
Abstract: A set of o-carborane-appended π-conjugated fluorophores and their light-emitting properties in the solid state are reported. The aggregation-induced emission enhancement (AIEE) exhibited for one of the fluorenyl derivatives paved the way to successfully preparing o-carborane-containing… read more here.
Keywords: fluorophores efficient; luminescent systems; carborane based; based fluorophores ... See more keywords
Conductance of o-carborane-based wires with different substitution patterns.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d3dt00011g
Abstract: Here, we report the synthesis, structure, and single-molecule conductance of three o-carborane-based molecular wires (ortho-, meta- and para-CN) with multiple conduction channels. The effect of connectivity in target wires compared with the corresponding phenyl-centered wires… read more here.
Keywords: conductance; based wires; carborane based; carborane ... See more keywords
The Synthesis, Properties, and Application of o-Carborane-based π-Conjugated Macrocycles
Sign Up to like & getrecommendations! Published in 2023 at "Organic Chemistry Frontiers"
DOI: 10.1039/d3qo00487b
Abstract: Two o-carborane-based π-conjugated macrocycles are synthesized via oxidative coupling of acetylene-terminated o-carborane precursors. The single-crystal X-ray diffraction analysis unambiguously revealed their unique porous supramolecular structures, which display micropore characteristics. The... read more here.
Keywords: conjugated macrocycles; carborane based; properties application; carborane ... See more keywords
Carborane-Based Analog of Rev-5901 Attenuates Growth of Colon Carcinoma In Vivo
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27144503
Abstract: Lipoxygenases convert polyunsaturated fatty acids into biologically active metabolites such as inflammatory mediators—prostaglandins and leukotrienes. The inhibition of lipoxygenases is increasingly employed in the treatment of cancer. We evaluated the anticancer potential of two novel… read more here.
Keywords: rev 5901; vivo; growth; carborane based ... See more keywords