Pd-Catalyzed Selective B(6)-H Phosphorization of nido-Carboranes via Cascade Deboronation/B-H Activation from closo-Carboranes.
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DOI: 10.1021/acs.inorgchem.2c00993
Abstract: Efficient Pd-catalyzed regioselective B(6)-H phosphorization of nido-carboranes via cascade deboronation/B-H activation of readily available C-substituted o-carboranes with various phosphines using 3-methylpyridine or isoquinoline as a directing group in combination with pyridine ligands has been developed,… read more here.
Keywords: cascade deboronation; phosphorization nido; nido; carboranes via ... See more keywords
Direct B-H Functionalization of Icosahedral Carboranes via Hydrogen Atom Transfer.
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DOI: 10.1021/jacs.3c01314
Abstract: The efficient and selective functionalization of icosahedral carboranes (C2B10H12) at the boron vertexes is a long-standing challenge owing to the presence of 10 inert B-H bonds in a similar chemical environment. Herein, we report a… read more here.
Keywords: hydrogen atom; functionalization; carboranes via; functionalization icosahedral ... See more keywords
A Strategy for Regioselective B−H Functionalization of o-Carboranes via Base Metal Catalysis
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DOI: 10.1039/d3qo00621b
Abstract: Carboranes, a class of carbon-boron molecular clusters, own unique characteristics and are finding a variety of applications ranging from materials to medicine. In this connection, selective functionalization of o-carboranes has... read more here.
Keywords: via base; functionalization; carboranes via; functionalization carboranes ... See more keywords