Synthesis of novel carboranyl azides and “click” reactions thereof
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2019.121007
Abstract: Abstract Novel nido-carboranyl azide [7-N3CH2CH2OCH2CH2O-7,8-C2B9H11]- was prepared by the reaction of 1-hydroxy-ortho-carborane with bis(2-chloroethyl) ether followed by the conversion to its nido-form and reactions with sodium iodide and sodium azide. Previously undescribed carboranyl azides 1-N3CH2CH2OCH2CH2S-1,2-C2B10H11… read more here.
Keywords: synthesis novel; carboranyl; click reactions; azides click ... See more keywords
Synthesis of an anionic Au(I) hydroamination precatalyst supported by charged hydrido-carboranyl phosphine ligands
Sign Up to like & getrecommendations! Published in 2018 at "Polyhedron"
DOI: 10.1016/j.poly.2018.09.027
Abstract: Abstract Herein is reported the synthesis of an anionic gold complex bearing two charged hydrido carboranyl phosphine ligands. The compound is fully characterized by multinuclear NMR spectroscopy, high resolution mass spectrometry, as well as a… read more here.
Keywords: carboranyl; hydrido carboranyl; charged hydrido; carboranyl phosphine ... See more keywords
Intramolecularly Stabilized o-Carboranyl Aluminum Complexes: Synthesis, Characterization, and X-ray Structural Studies
Sign Up to like & getrecommendations! Published in 2023 at "Crystals"
DOI: 10.3390/cryst13060877
Abstract: The chelating aluminum complex [2-(Me2NCH2)C2B10H10]AlX2 (X = Br 3, CH3 4) was synthesized using 2-dimethylaminomethyl-o-carboranyl lithium (LiCabN, 2) with aluminum tribromide (AlBr3) or dimethylaluminum bromide (Me2AlBr), resulting in a modest yield. Compound 4 was obtained by… read more here.
Keywords: structural studies; aluminum complexes; aluminum; spectroscopy ... See more keywords