Cu(II) carboxylate arene C─H functionalization: Tuning for nonradical pathways
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DOI: 10.1126/sciadv.add1594
Abstract: We report carbon-hydrogen acetoxylation of nondirected arenes benzene and toluene, as well as related functionalization with pivalate and 2-ethylhexanoate ester groups, using simple copper(II) [Cu(II)] salts with over 80% yield. By changing the ratio of… read more here.
Keywords: carboxylate arene; tuning nonradical; functionalization; arene functionalization ... See more keywords