Mechanistic Investigation of Bis(imino)pyridine Manganese Catalyzed Carbonyl and Carboxylate Hydrosilylation.
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DOI: 10.1021/jacs.7b00879
Abstract: We recently reported a bis(imino)pyridine (or pyridine diimine, PDI) manganese precatalyst, (Ph2PPrPDI)Mn (1), that is active for the hydrosilylation of ketones and dihydrosilylation of esters. In this contribution, we reveal an expanded scope for 1-mediated… read more here.
Keywords: imino pyridine; bis imino; carboxylate hydrosilylation; catalyzed carbonyl ... See more keywords