Monomer, chain, layer and 3-D framework constructed by linear 4′-(4-carboxyphenyl)-2,2′:6′,2″-terpyridine
Sign Up to like & getrecommendations! Published in 2018 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2018.07.006
Abstract: Abstract Assembly of functional 4′-(4-carboxyphenyl)-2,2′:6′,2″-terpyridine (Htyba) with transition metal and/or lanthanide salts, monomer of Ni(Htyba)2(NO3)2·5H2O (1), homometallic chains of {[Cu(tyba)(NO3)]·H2O}n (2) and [Pr(tyba)3]n (3), heterometallic layers of {[LnM(tyba)2(p-bdc)0.5(NO3)2]·2H2O}n (4–8) and three-dimensional heterometallic frameworks of {[LnCu(Htyba)(tyba)(m-bdc)(NO3)]NO3}n… read more here.
Keywords: carboxyphenyl terpyridine; monomer chain; bdc no3; carboxyphenyl ... See more keywords
Four coordination polymers based on 4'-(4-carboxyphenyl)-2,2':6',2''-terpyridine: Syntheses, structures and properties
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DOI: 10.1016/j.jssc.2018.09.019
Abstract: Abstract Four coordination polymers, [CuCl(cptpy)·2H2O]n (1), [Mn2Cl2(cptpy)2(phdat)H2O]n (2) and [Ln(cptpy)3]n (Ln = La (3), Pr (4)) (Hcptpy = 4'-(4-carboxyphenyl)-2,2':6',2''-terpyridine, phdat = 2,4-diamino-6-phenyl-triazine) have been hydrothermally synthesized and characterized by IR spectra, X-ray single-crystal diffraction, powder X-ray… read more here.
Keywords: four coordination; polymers based; coordination polymers; carboxyphenyl terpyridine ... See more keywords
Two metal–organic frameworks based on carboxyphenyl–terpyridine ligands: Synthesis, structure and highly luminescent sensing of nitrobenzene
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DOI: 10.1016/j.poly.2018.06.028
Abstract: Abstract Two metal–organic frameworks, [Cu(cptpy)(NO3)]·DMF·2H2O (1) and [Zn3(cptpy)3(NO3)2(H2O)4]·NO3·5DMF·2H2O (2), were solvothermally obtained with carboxyphenyl–terpyridine ligand (4-(4-carboxyphenyl)-2,2′:4′,4″-terpyridine) (Hcptpy). Complex 1 reveals a 3D 4-fold interpenetrating network with ths topology, and complex 2 exhibits a 2D layer… read more here.
Keywords: carboxyphenyl terpyridine; two metal; metal organic; topology ... See more keywords
Metal-Organic Framework Photocatalyst Incorporating Bis(4'-(4-carboxyphenyl)-terpyridine)ruthenium(II) for Visible-Light-Driven Carbon Dioxide Reduction.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b01920
Abstract: In this study, we report the successful incorporation of the photoactive bis(4'-(4-carboxyphenyl)-terpyridine)ruthenium(II) (Ru(cptpy)2) strut into a robust metal-organic framework (MOF), AUBM-4. The single crystal X-ray analysis revealed the formation of a new one-dimensional structure of Ru(cptpy)2… read more here.
Keywords: bis carboxyphenyl; carboxyphenyl terpyridine; metal organic; carbon dioxide ... See more keywords