Carvone-Derived P-Stereogenic Phosphines: Design, Synthesis, and Use in Allene-Imine [3 + 2] Annulation.
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DOI: 10.1021/acscatal.8b01081
Abstract: We have prepared a previously unreported family of P-stereogenic [2.2.1] bicyclic chiral phosphines through straightforward syntheses starting from the natural product carvone. This design rationale prompted the development of an unforeseen C-dealkenylation reaction. We have… read more here.
Keywords: derived stereogenic; phosphines design; carvone derived; carvone ... See more keywords