A divergent [5+2] cascade approach to bicyclo[3.2.1]octanes: facile synthesis of ent-kaurene and cedrene-type skeletons.
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DOI: 10.1039/c7cc04292b
Abstract: A solvent-dependent oxidative dearomatization-induced divergent [5+2] cascade approach to bicyclo[3.2.1]octanes was described. This novel protocol enables a facile synthesis of a series of diversely functionalized ent-kaurene and cedrene-type skeletons in good yields and excellent diastereoselectivities. read more here.
Keywords: approach bicyclo; cascade approach; bicyclo octanes; facile synthesis ... See more keywords
Palladium-Catalyzed Cascade Approach to 12-(Aryl)indolo[1,2-c]quinazolin-6(5H)-ones
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DOI: 10.1055/s-0036-1589158
Abstract: A straightforward one-pot approach to the synthesis of challenging 12-arylindolo[1,2-c]quinazolin-6(5H)-ones is described. Starting from readily available o-(o-aminophenylethynyl)trifluoroacetanilides, palladium-catalyzed aminoarylation of the triple bond with ArI, ArBr, and ArN2 +BF4 – is followed by cyclization of… read more here.
Keywords: cascade approach; palladium catalyzed; approach; catalyzed cascade ... See more keywords
An Alternative Exploitation of Synechocystis sp. PCC6803: A Cascade Approach for the Recovery of High Added-Value Products
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DOI: 10.3390/molecules28073144
Abstract: Microalgal biomass represents a very interesting biological feedstock to be converted into several high-value products in a biorefinery approach. In this study, the cyanobacterium Synechocystis sp. PCC6803 was used to obtain different classes of molecules:… read more here.
Keywords: value products; cascade approach; synechocystis pcc6803; synechocystis ... See more keywords