Samarium Diiodide Catalyzed Radical Cascade Cyclizations that Construct Quaternary Stereocenters
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DOI: 10.1055/s-0039-1690196
Abstract: SmI2-catalyzed radical cascade cyclizations were used to generate complex carbocyclic products bearing quaternary stereocenters with high selectivity. Bicyclic scaffolds containing four contiguous stereocenters and one quaternary stereocenter were obtained in excellent yields (up to 99%)… read more here.
Keywords: radical cascade; cascade cyclizations; quaternary stereocenters; catalyzed radical ... See more keywords