Pd-Catalyzed Selective B(6)-H Phosphorization of nido-Carboranes via Cascade Deboronation/B-H Activation from closo-Carboranes.
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DOI: 10.1021/acs.inorgchem.2c00993
Abstract: Efficient Pd-catalyzed regioselective B(6)-H phosphorization of nido-carboranes via cascade deboronation/B-H activation of readily available C-substituted o-carboranes with various phosphines using 3-methylpyridine or isoquinoline as a directing group in combination with pyridine ligands has been developed,… read more here.
Keywords: cascade deboronation; phosphorization nido; nido; carboranes via ... See more keywords