Radical Cascade Dissociation Pathways to Unusual Nucleobase Cation Radicals.
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DOI: 10.1021/jasms.2c00098
Abstract: We report unusual dissociations of protonated RNA nucleosides tagged with radical initiator groups at ribose 5'-O and furnished with a 2',3'-O-isopropylidene protecting group. The ions undergo collision-induced radical cascade dissociations starting at the radical initiator… read more here.
Keywords: cation radicals; cascade; cascade dissociations; radical cascade ... See more keywords