Selective conversion of HMF into 3-hydroxymethylcyclopentylamine through a one-pot cascade process in aqueous phase over bimetallic NiCo nanoparticles as catalyst.
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DOI: 10.1002/cssc.202200194
Abstract: 5-hydroxymethylfurfural (HMF) has been successfully valorised into 3-hydroxymethyl cyclopentylamine through a one-pot cascade process in aqueous phase by coupling the hydrogenative ring-rearrangement of HMF into 3-hydroxymethylcyclopentanone (HCPN) followed by the reductive amination with ammonia. Mono… read more here.
Keywords: pot cascade; one pot; aqueous phase; hmf ... See more keywords
Integrated Cascade Process for the Catalytic Conversion of 5âHydroxymethylfurfural to Furanic and TetrahydrofuranicDiethers as Potential Biofuels
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DOI: 10.1002/cssc.202200241
Abstract: Abstract The depletion of fossil resources is driving the research towards alternative renewable ones. Under this perspective, 5âhydroxymethylfurfural (HMF) represents a key molecule deriving from biomass characterized by remarkable potential as platform chemical. In this… read more here.
Keywords: catalytic conversion; cascade process; process; process catalytic ... See more keywords
Photoredox Catalysis toward 2-Sulfenylindole Synthesis through a Radical Cascade Process.
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DOI: 10.1021/acs.orglett.0c01297
Abstract: A radical cascade process initiated through visible-light induced thiyl radical coupling with ortho-substituted arylisocianides followed by an intramolecular cyclization and subsequent aromatization to access 2-sulfenylindoles is described. The key thiyl radicals are promptly generated via… read more here.
Keywords: radical cascade; cascade process; process; catalysis toward ... See more keywords
SO2F2-Mediated one-pot cascade process for transformation of aldehydes (RCHO) to cyanamides (RNHCN)
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DOI: 10.1039/d0ra02631j
Abstract: A simple, mild and practical cascade process for the direct conversion of aldehydes to cyanamides was developed featuring a wide substrate scope and great functional group tolerability. This method allows for transformations of readily available,… read more here.
Keywords: mediated one; cascade process; cascade; so2f2 mediated ... See more keywords