Palladium-catalysed aminocarbonylation/cyclization of iodoalkenes toward N-propargylcarboxamides and oxazoles
Sign Up to like & getrecommendations! Published in 2018 at "Molecular Catalysis"
DOI: 10.1016/j.mcat.2018.03.015
Abstract: Abstract Palladium(0) complexes formed in situ from a palladium(II) precursor, Pd(OAc)2, proved to be highly active catalytic system in aminocarbonylation of the variety of iodoalkenes (1-iodocyclohexene, 4-tert-butyl-1-iodocyclohexene, 2-methyl-1-iodocyclohexene, α-iodostyrene, 2-iodobornene, 17-iodoandrost-16-ene, 17-iodo-3-methoxyestra-1,3,5(10),16-tetraene, 20-iodo-3β-hydroxypregna-5,20-diene) using propargylamine… read more here.
Keywords: palladium; aminocarbonylation cyclization; palladium catalysed; catalysed aminocarbonylation ... See more keywords
Synthesis of benzamide-benzothiazole conjugates via palladium-catalysed aminocarbonylation (hydrazinocarbonylation)
Sign Up to like & getrecommendations! Published in 2019 at "Tetrahedron"
DOI: 10.1016/j.tet.2019.02.026
Abstract: Abstract The palladium-catalysed aminocarbonylation of iodoarenes was investigated using 2-amino- and 2-hydrazinobenzothiazole as N-nucleophile. The reaction proved to be highly chemoselective in all cases: carboxamides and the corresponding carbohydrazides, obtained by the acylation at the… read more here.
Keywords: synthesis benzamide; catalysed aminocarbonylation; palladium catalysed;