Theoretical study of FMO adjusted C-H cleavage and oxidative addition in nickel catalysed C-H arylation
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DOI: 10.1038/s42004-019-0132-5
Abstract: Nickel catalysis has recently emerged as an important addition to the suite of transition metal-catalysed C-H bond functionalization methods. Here we report density functional theory calculations to elucidate the mechanism of Ni(II)-catalysed C–H arylation with… read more here.
Keywords: addition; cleavage; bond; oxidative addition ... See more keywords
Palladium-catalysed C–H arylation of benzophospholes with aryl halides
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DOI: 10.1039/d2sc04311d
Abstract: A palladium-catalysed C–H arylation of benzophospholes with aryl halides has been developed. The reaction with aryl iodides and bromides proceeds well even under phosphine ligand-free Pd(OAc)2 catalysis whereas the Pd(PCy3)2 is effective for the coupling… read more here.
Keywords: palladium catalysed; benzophospholes aryl; aryl halides; catalysed arylation ... See more keywords