Ruthenium(ii)-catalysed direct synthesis of ketazines using secondary alcohols.
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DOI: 10.1039/c9cc01383k
Abstract: Direct one-pot synthesis of ketazines from secondary alcohols and hydrazine hydrate catalyzed by a ruthenium pincer complex is reported, which proceeds through O-H bond activation of secondary alcohols via amine-amide metal-ligand cooperation in the catalyst.… read more here.
Keywords: direct synthesis; secondary alcohols; synthesis ketazines; catalysed direct ... See more keywords
Nickel-catalysed direct α-olefination of alkyl substituted N-heteroarenes with alcohols.
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DOI: 10.1039/c9cc03591e
Abstract: Catalytic α-olefination of alkylheteroarenes with primary alcohols via dehydrogenative coupling is presented. A simple nickel catalyst system stabilised by readily available nitrogen ligands enables a series of interesting E-configured vinylarenes (confirmed by X-ray crystal-structure analysis)… read more here.
Keywords: alkyl substituted; nickel catalysed; olefination; catalysed direct ... See more keywords
Rhodium-catalysed direct formylmethylation using vinylene carbonate and sequential dehydrogenative esterification.
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DOI: 10.1039/d1cc03362j
Abstract: A rhodium-catalysed direct formylmethylation adopting vinylene carbonate as an ethynol equivalent is reported. The developed catalytic system is further utilised for the oxidant-free production of esters with the liberation of hydrogen gas. Some control experiments… read more here.
Keywords: direct formylmethylation; rhodium catalysed; vinylene carbonate; catalysed direct ... See more keywords
Photoinduced, copper-catalysed direct perfluoroalkylation of heteroarenes.
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DOI: 10.1039/d2cc02146c
Abstract: An efficient and general process is reported for the photoinduced, copper-catalysed direct perfluoroalkylation of C-H bonds in a broad range of heteroarenes with commercially available perfluoroalkyl iodides. This redox neutral process is simply based on… read more here.
Keywords: direct perfluoroalkylation; copper catalysed; photoinduced copper; catalysed direct ... See more keywords
Turning Pd-Catalysed Direct C–H Arylation of Thiophene Derivatives into Green: Industrial Wastewater as an Effective Reaction Medium
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DOI: 10.1039/d4gc01139b
Abstract: The Pd-catalysed direct C–H arylation of thiophene derivatives, appealing for technological application, is performed under green conditions, using water as the sole reaction medium. The reaction is independent of the... read more here.
Keywords: reaction; arylation thiophene; direct arylation; thiophene derivatives ... See more keywords