The Cu(i)-catalysed Huisgen 1,3-dipolar cycloaddition route to (bio-)organic functionalisation of polyoxovanadates.
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DOI: 10.1039/c7dt03376a
Abstract: The [V6O13{(OCH2)3CCH2OCH2C[triple bond, length as m-dash]CH}2]2- with two terminal alkyne functionalities exhibits excellent reactivity towards (bio-)organic azides. The designed synthetic protocol for the generation of triazol-modified Lindqvist hexavanadates grants access to bio-"clicked" polyoxometalates with spectroscopically… read more here.
Keywords: bio organic; catalysed huisgen; bio; cycloaddition route ... See more keywords