Iron-catalysed reductive coupling for the synthesis of polyfluorinated compounds.
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DOI: 10.1039/d2cc06022a
Abstract: Herein we reported the use of Earth-abundant iron as the catalytic metal in the presence of Mn to induce difluorobromoacetates to form carbon radicals, which reacted with trifluoromethyl olefins followed by β-F elimination to generate… read more here.
Keywords: catalysed reductive; iron; reductive coupling; coupling synthesis ... See more keywords