Cross-coupling reactions by cooperative Pd/Cu or Ni/Cu catalysis based on the catalytic generation of organocopper nucleophiles
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DOI: 10.1016/j.tet.2018.12.013
Abstract: Abstract In this review, cross-coupling reactions by cooperative Pd/Cu or Ni/Cu catalysis based on catalytically generated organocopper nucleophiles are summarized. Compared to conventional methods based on the use of stoichiometric amounts of pre-synthesized organometallic reagents,… read more here.
Keywords: cross coupling; catalysis based; organocopper nucleophiles; cooperative catalysis ... See more keywords
Catalysis-Based Total Syntheses of Pateamine A and DMDA-Pat A.
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DOI: 10.1021/jacs.8b05094
Abstract: The marine natural product pateamine A (1) and its somewhat simplified designer analogue DMDA-Pat A (2) (DMDA = desmethyl-desamino) are potently cytotoxic compounds; most notably, 2 had previously been found to exhibit a promising differential… read more here.
Keywords: dmda pat; total syntheses; pat; catalysis based ... See more keywords
Catalysis based on ferroelectrics: controllable chemical reaction with boosted efficiency.
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DOI: 10.1039/d1nr00847a
Abstract: Catalysts, which can accelerate chemical reactions, show promising potential to alleviate environmental pollution and the energy crisis. However, their wide application is severely limited by their low efficiency and poor selectivity due to the recombination… read more here.
Keywords: catalysis; based ferroelectrics; efficiency; chemical reaction ... See more keywords