Dual Cobalt and Photoredox Catalysis Enabled Intermolecular Oxidative Hydrofunctionalization
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DOI: 10.1021/acscatal.0c01209
Abstract: A general protocol has been developed for the Markovnikov-selective intermolecular hydrofunctionalization based on visible-light-mediated Co/Ru dual catalysis. The key feature involves the photoche... read more here.
Keywords: dual cobalt; hydrofunctionalization; catalysis; catalysis enabled ... See more keywords
Catalysis-Enabled 13-Step Total Synthesis of (-)-Peyssonnoside A.
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DOI: 10.1021/jacs.2c09919
Abstract: We report a 13-step enantioselective and stereoselective total synthesis of (-)-peyssonnoside A, a unique diterpene glucoside with a rare and highly congested pentasubstituted cyclopropane and promising antimicrobial activity. Among the 10 steps to synthesize (-)-peyssonnosol,… read more here.
Keywords: step; synthesis peyssonnoside; peyssonnoside; catalysis enabled ... See more keywords
Micellar catalysis-enabled sustainable ppm Au-catalyzed reactions in water at room temperature† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc02405c Click here for additional data file.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical Science"
DOI: 10.1039/c7sc02405c
Abstract: Several ppm level gold-catalyzed reactions enabled by the ligand HandaPhos can be performed at room temperature in aqueous nanoreactors composed of the surfactant Nok. read more here.
Keywords: catalyzed reactions; catalysis enabled; room temperature; micellar catalysis ... See more keywords
Catalysis enabled synthesis, structures, and reactivities of fluorinated S8-corona[n]arenes (n = 8–12)
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DOI: 10.1039/d2sc05348a
Abstract: Previously inaccessible large S8-corona[n]arene macrocycles (n = 8–12) with alternating aryl and 1,4-C6F4 subunits are easily prepared on up to gram scales, without the need for chromatography (up to 45% yield, 10 different examples) through… read more here.
Keywords: catalysis; enabled synthesis; reactivities fluorinated; structures reactivities ... See more keywords