Articles with "catalysis radical" as a keyword



Photo by alecs from unsplash

Reduction of SF5CF3via iridium catalysis: radical trifluoromethylation of aromatics.

Sign Up to like & get
recommendations!
Published in 2023 at "Chemical communications"

DOI: 10.1039/d3cc00495c

Abstract: The greenhouse gas SF5CF3 acts as CF3 source for the photocatalytic trifluoromethylation of arenes on using [Ir(dtbbpy)(ppy)2]PF6 (4,4'-di-tert-butyl-2,2'-dipyridyl, ppy = 2-phenylpyridine) as catalyst. The trifluoromethylation of C6D6 in the presence of 1-octanol results in the… read more here.

Keywords: catalysis radical; radical trifluoromethylation; sf5cf3via iridium; reduction sf5cf3via ... See more keywords