Unraveling the sigmoidal profiles in Fenton catalysis: Toward mechanistic elucidation
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2018.01.031
Abstract: Abstract Fenton reactions are widely known and have been employed to degrade different pollutants in various environmental matrices. However, some controversies related to the Fenton mechanism remain unresolved. Although not comprehensively understood, kinetic sigmoidal profiles… read more here.
Keywords: fenton catalysis; profiles fenton; sigmoidal profiles; catalysis ... See more keywords
Photoredox Catalysis toward 2-Sulfenylindole Synthesis through a Radical Cascade Process.
Sign Up to like & getrecommendations! Published in 2020 at "Organic letters"
DOI: 10.1021/acs.orglett.0c01297
Abstract: A radical cascade process initiated through visible-light induced thiyl radical coupling with ortho-substituted arylisocianides followed by an intramolecular cyclization and subsequent aromatization to access 2-sulfenylindoles is described. The key thiyl radicals are promptly generated via… read more here.
Keywords: radical cascade; cascade process; process; catalysis toward ... See more keywords