Ternary intermetallic LaCoSi as a catalyst for N2 activation
Sign Up to like & getrecommendations! Published in 2018 at "Nature Catalysis"
DOI: 10.1038/s41929-017-0022-0
Abstract: AbstractActivating high-energy multiple bonds using earth-abundant metals is one of the most significant challenges in catalysis. Here, we show that LaCoSi—a ternary intermetallic compound—is an efficient and stable catalyst for N2 activation to produce NH3.… read more here.
Keywords: ternary intermetallic; energy; lacosi; catalyst activation ... See more keywords
Thermodynamics of metallocene catalyst activation: alignment of theory and experiment.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01711c
Abstract: Three equilibria involved in metallocene catalyst activation, including dissociation of R6Al2 (R = Me, Et or i-Bu) and related species such as [L2ZrMe2AlMe2][B(C6F5)4] (L2 = Cp2, 1,2-ethylenebis(η5-indenyl), Me2C(η5-C5H4)2) or [(L2ZrMe)2μ-Me][MePBB] (L2 = (h5-1,2-Me2C5H3)2, [MePBB]- =… read more here.
Keywords: catalyst activation; thermodynamics; theory experiment; alignment theory ... See more keywords
Modeling the Catalyst Activation Step in a Metal–Ligand Radical Mechanism Based Water Oxidation System
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DOI: 10.3390/inorganics7050062
Abstract: Designing catalysts for water oxidation (WOCs) that operate at low overpotentials plays an important role in developing sustainable energy conversion schemes. Recently, a mononuclear ruthenium WOC that operates via metal–ligand radical coupling pathway was reported,… read more here.
Keywords: activation; ligand radical; step; catalyst activation ... See more keywords