Hydroxylated Polyoxometalate with Cu(II)- and Cu(I)-Aqua Complexes: A Bifunctional Catalyst for Electrocatalytic Water Splitting at Neutral pH.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c00423
Abstract: A sole inorganic framework material [Li(H2O)4][{CuI(H2O)1.5} {CuII(H2O)3}2{WVI12O36(OH)6}]·N2·H2S·3H2O (1) consisting of a hydroxylated polyoxometalate (POM) anion, {WVI12O36(OH)6}6-, a mixed-valent Cu(II)- and Cu(I)-aqua cationic complex species, [{CuI(H2O)1.5}{CuII(H2O)3}2]5+, a Li(I)-aqua complex cation, and three solvent molecules, has been… read more here.
Keywords: aqua; water; bifunctional catalyst; catalyst electrocatalytic ... See more keywords
A metal-free catalyst for electrocatalytic NO reduction to NH3.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d3dt00994g
Abstract: Metal-free boron phosphide (BP) is explored for the first time as an effective catalyst for electrocatalytic NO reduction to NH3, showing a high NH3-faradaic efficiency of 83.3% with an NH3 yield rate of 96.6 μmol… read more here.
Keywords: catalyst electrocatalytic; metal free; reduction nh3; electrocatalytic reduction ... See more keywords