A Heterogeneous Iridium Catalyst for the Hydroboration of Pyridines.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c01859
Abstract: Sulfated zirconium oxide (SZO) capped with silylium-like ions reacts with (cod)Ir(py)Cl (cod = 1,5-cyclooctadiene; py = pyridine) to form [Ir(cod)py][SZO] (1) and Me3SiCl. 1 can also be formed in reactions of phosphonium functionalized SZO and… read more here.
Keywords: catalyst hydroboration; iridium catalyst; pyridine; hydroboration ... See more keywords
A phenalenyl-based nickel catalyst for the hydroboration of olefins under ambient conditions.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt00468h
Abstract: In this report, nickel-catalyzed hydroboration of vinylarenes and aliphatic alkenes is investigated. The non-innocent phenalenyl ligand moiety in the nickel complex Ni(PLY)2(THF)2 (1) was utilized as an electron reservoir for the selective hydroboration reaction in… read more here.
Keywords: based nickel; catalyst hydroboration; nickel catalyst; ambient conditions ... See more keywords