Chemoselective Hydrogenation with Supported Organoplatinum(IV) Catalyst on Zn(II)-Modified Silica.
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DOI: 10.1021/jacs.7b11981
Abstract: Well-defined organoplatinum(IV) sites were grafted on a Zn(II)-modified SiO2 support via surface organometallic chemistry in toluene at room temperature. Solid-state spectroscopies including XAS, DRIFTS, DRUV-vis, and solid-state (SS) NMR enhanced by dynamic nuclear polarization (DNP),… read more here.
Keywords: hydrogenation; catalyst modified; hydrogenation supported; chemoselective hydrogenation ... See more keywords