Robust acid–base Ln-MOFs: searching for efficient catalysts in cycloaddition of CO2 with epoxides and cascade deacetalization–Knoevenagel reactions
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DOI: 10.1039/d2ra06545b
Abstract: A family of microporous and robust Ln(iii)-based metal–organic frameworks (1-Ln, Ln = Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb) have been obtained using 4,4′,4′′-nitrilotribenzoic acid (H3NTB) in NMP–HCl solvent. Both single-crystal and powder X-ray… read more here.
Keywords: catalysts cycloaddition; acid base; cascade deacetalization; knoevenagel reactions ... See more keywords