Novel olefin metathetis catalysts with fluorinated N-alkyl-N´-arylimidazolin-2-ylidene ligands
Sign Up to like & getrecommendations! Published in 2017 at "Russian Chemical Bulletin"
DOI: 10.1007/s11172-017-1930-5
Abstract: Novel ruthenium carbene complexes bearing unsymmetrical NHC-ligands based on N-alkyl-N´-arylimidazoline with hexafluoroisopropylmethoxy group in para-position of N-aryl moiety have been synthesized. Catalytic activity of complexes obtained was investigated on model reactions of intra- and intermolecular… read more here.
Keywords: olefin; fluorinated alkyl; metathetis catalysts; olefin metathetis ... See more keywords
New olefin metathesis catalysts with fluorinated unsymmetrical imidazole-based ligands
Sign Up to like & getrecommendations! Published in 2018 at "Mendeleev Communications"
DOI: 10.1016/j.mencom.2018.11.015
Abstract: New olefin metathesis catalysts, unsaturated analogues of the Grubbs II and Hoveyda–Grubbs II ones, bearing bulky (alkoxy)hexafluoroisopropyl groups in one of the aryl substituent of NHC ligand provide high conversions in model ring closing metathesis… read more here.
Keywords: olefin metathesis; fluorinated unsymmetrical; catalysts fluorinated; new olefin ... See more keywords