Macrocyclic Pd(II) dithiolate complexes as catalysts in Heck reactions
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DOI: 10.1016/j.tetlet.2016.11.085
Abstract: Abstract The supramolecular palladium dithiolate complexes, [Pd2(dppe)2{S(C6H4)nS}]2(OTf)4 and [Pd2(dppe)2(SCH2C6H4CH2S)]4(OTf)8 (dppe = 1,2-bis(diphenylphosphino)ethane) has been investigated as highly stable and robust catalysts in Heck C-C coupling reactions. The arylation of butyl acrylate and styrene with various aryl bromides… read more here.
Keywords: heck reactions; complexes catalysts; catalysts heck; dithiolate complexes ... See more keywords