Platinum Complexes with Chelating Acyclic Aminocarbene Ligands Work as Catalysts for Hydrosilylation of Alkynes
Sign Up to like & getrecommendations! Published in 2018 at "ACS Omega"
DOI: 10.1021/acsomega.7b01688
Abstract: This work describes the preparation of a series of platinum–aminocarbene complexes [PtCl{C(N=Ca(C6R2R3R4R5CONb))=N(H)R1}(CNR1)]a–b (8–19, 65–75% isolated yield) via the reaction of cis-[PtCl2(CNR1)2] (R1 = Cy 1, t-Bu 2, Xyl 3, 2-Cl-6-MeC6H34) with 3-iminoisoindolin-1-ones HN=Ca(C6R2R3R4R5CONbH) (R2–R5 =… read more here.
Keywords: work; aminocarbene; platinum; catalysts hydrosilylation ... See more keywords
Tying Covalent Organic Frameworks through Alkene Metathesis and Supported Platinum as Efficient Catalysts for Hydrosilylation
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DOI: 10.3390/nano12030499
Abstract: Recently there has been a great interest in covalent organic frameworks due to their fascinating properties. Current approaches to improve their hydrolytic stability mainly rely on the transformation of the dynamic bonds into strong and… read more here.
Keywords: organic frameworks; metathesis; efficient catalysts; catalysts hydrosilylation ... See more keywords