Synthesis of New Pd(NHC)-PEPPSI Type Complexes as Catalysts toward C-C Cross-Coupling Reactions
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2021.130883
Abstract: Abstract The goal of our research is to synthesis homogeneous catalysts, for which we take start from two novel precursors of 1-(3-methyloxetane-3-yl)benzimidazole and 5,6-dimethyl-1-((3-methyloxetane-3-yl)benzimidazole. A series of ligands containing 1,3-disubstituted benzimidazolium salts were synthesized from… read more here.
Keywords: nhc peppsi; type complexes; catalysts toward; peppsi type ... See more keywords
Insights into the ligand effects of rhodium catalysts toward reductive carbonylation of methanol to ethanol
Sign Up to like & getrecommendations! Published in 2017 at "RSC Advances"
DOI: 10.1039/c7ra10739k
Abstract: Methanol reductive carbonylation to ethanol catalyzed by diphosphine ligand modified Rh-based catalysts has been studied. All the catalysts show ligand effects toward the turnover frequency and selectivity. Four Rh–diphosphine complexes were isolated and single crystals… read more here.
Keywords: catalysts toward; ligand effects; reductive carbonylation; effects rhodium ... See more keywords