Catalytic Aerobic Cross-Dehydrogenative Coupling of Phenols and Catechols
Sign Up to like & getrecommendations! Published in 2019 at "ACS Catalysis"
DOI: 10.1021/acscatal.8b04443
Abstract: We describe a selective, catalytic aerobic cross-dehydrogenative coupling (CDC) reaction of phenols and catechols that creates aryl ethers. To avoid challenges of selectivity, we employ copper (Cu) coordination to confine substrate redox to the inner… read more here.
Keywords: cross dehydrogenative; phenols catechols; catalytic aerobic; cross ... See more keywords
Efficient Syntheses of Biobased Terephthalic Acid, p-Toluic Acid, and p-Methylacetophenone via One-Pot Catalytic Aerobic Oxidation of Monoterpene Derived Bio-p-cymene
Sign Up to like & getrecommendations! Published in 2021 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.1c02605
Abstract: An efficient elevated-pressure catalytic oxidative process (2.5 mol % Co(NO3)2, 2.5 mol % MnBr2, air (30 bar), 125 °C, acetic acid, 6 h) has been developed to oxidize p-cymene into crystalline white terephthalic acid (TA)… read more here.
Keywords: oxidation; terephthalic acid; acid; cymene ... See more keywords
Influence of the channel size of isostructural 3d–4f MOFs on the catalytic aerobic oxidation of cycloalkenes
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DOI: 10.1039/c9nj02091h
Abstract: The present work reports a new group of heterogeneous catalysts with a 3D structure, CuLnIDA, {[Cu3Ln2(IDA)6]·8H2O} (Ln: LaIII, GdIII or YbIII), with an organic linker (H2IDA: iminodiacetic acid). read more here.
Keywords: size isostructural; mofs catalytic; isostructural mofs; channel size ... See more keywords